52.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 09.03.2021 *
Version number 25
Revision: 09.03.2021
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: AQUAFIN-RB400 (A-Komp.) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Sealing · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 email: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Irrit. 2 H315 Causes skin irritation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals · Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. · Precautionary statements P264 Wash thoroughly after handling. P280 Wear protective gloves / eye protection / face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs: Get medical advice/attention. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 09.03.2021
Trade name: AQUAFIN-RB400 (A-Komp.) (Contd. of page 1)
· vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Preparation based on special cement and additives. · Dangerous components: CAS: 65997-15-1 Cement, portland, chemicals EINECS: 266-043-4 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335 · Additional information For the wording of the listed hazard phrases refer to section 16.
10-25%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact After contact, clean the skin mechanical and rinse with water and soap. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. *
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Prevent formation of dust. Keep away from children. (Contd. on page 3) GB
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Trade name: AQUAFIN-RB400 (A-Komp.) (Contd. of page 2)
· Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: None. · Storage class 13 · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (10-25%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with eyes and skin. Change clothes which heavy contaminate with the product. Wash hands during breaks and at the end of the work. · Breathing equipment: Not required. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Safety glasses · Body protection: Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Solid · Colour: grey · Smell: Characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range not apply · Flammability Not determined. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. (Contd. on page 4) GB
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Trade name: AQUAFIN-RB400 (A-Komp.) (Contd. of page 3)
· Flash point: · Self-inflammability: · Decomposition temperature: · pH at 20 °C · Viscosity: · Kinematic viscosity · dynamic: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density · Relative density · Settled apparent density · Vapour density
Not applicable Product is not selfigniting. Not determined. 11.3 (1%) Not applicable. Not applicable. miscible Not determined. Not applicable. bulk density Not determined. 1.25 kg/dm³ Not applicable.
· 9.2 Other information · Appearance: · Form: Solid material. · Important information on protection of health and environment, and on safety. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not applicable. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. (Contd. on page 5) GB
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Trade name: AQUAFIN-RB400 (A-Komp.) (Contd. of page 4)
· 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1317-65-3 Calciumcarbonat Oral LD50 >5,000 mg/kg (rats) · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed.
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1317-65-3 Calciumcarbonat LC50/96h >10,000 mg/l (rainbow trout) EC50 (48h) >1,000 mg/l (Daphnia magna) EC50 289 mg/l /72h (Desmodesmus subspicatus) NOEC 75 mg/l /72h (Desmodesmus subspicatus) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. GB
(Contd. on page 6)
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Trade name: AQUAFIN-RB400 (A-Komp.) (Contd. of page 5)
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 17 00 00 CONSTRUCTION AND DEMOLITION WASTES (INCLUDING EXCAVATED SOIL FROM CONTAMINATED SITES) 17 01 00 concrete, bricks, tiles and ceramics 17 01 07 mixtures of concrete, bricks, tiles and ceramics other than those mentioned in 17 01 06 HP4 Irritant - skin irritation and eye damage · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent.
SECTION 14: Transport information · 14.1 UN number or ID number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronic equipment – Annex II None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. (Contd. on page 7) GB
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Trade name: AQUAFIN-RB400 (A-Komp.) (Contd. of page 6)
· Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Date of previous version: 09.03.2021 · Version number of previous version: 24 · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered. GB