44.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 04.01.2017 *
Version number 10
Revision: 04.01.2017
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-SG2 (A-Komp.)(INDUFLOOR-IB 1240 (A-Komp.)) · Article number: 205655 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labelling: reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) 1,6-bis(2,3-ethoxypropoxy)hexane · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 04.01.2017
Trade name: ASODUR-SG2 (A-Komp.)(INDUFLOOR-IB 1240 (A-Komp.)) (Contd. of page 1)
P363 P333+P313 P501
Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: Contains epoxy constituents. May produce an allergic reaction. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight ≤ 700. · Dangerous components: CAS: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number NLP: 500-033-5 average molecular weight ≤ 700) Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 CAS: 16096-31-4
1,6-bis(2,3-ethoxypropoxy)hexane Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; Aquatic Chronic 3, H412
10-25%
CAS: 64742-95-6 Solvent naphtha (petroleum), light arom. < 1% EINECS: 265-199-0 Flam. Liq. 3, H226; Muta. 1B, H340; Carc. 1B, H350; Asp. Tox. 1, H304 SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air and call for doctor for safety reasons. In case of unconsciousness bring patient into stable side position for transport. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: No special measures required. GB
(Contd. on page 3)
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Trade name: ASODUR-SG2 (A-Komp.)(INDUFLOOR-IB 1240 (A-Komp.)) (Contd. of page 2)
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Not required. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal.
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. · Breathing equipment: Not required. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing. GB
(Contd. on page 4)
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Trade name: ASODUR-SG2 (A-Komp.)(INDUFLOOR-IB 1240 (A-Komp.)) (Contd. of page 3)
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: According to product specification · Smell: Characteristic · Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
> 100 °C
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Steam pressure:
Not determined.
· Density at 20 °C
1.98 g/cm³
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Viscosity: dynamic at 20 °C: kinematic: · 9.2 Other information
1800 mPas Not determined. No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 13462-86-7 Barytmehl N Oral LD50 >15000 mg/kg (rats) 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) Oral LD50 >5000 mg/kg (rats) Dermal LD50 >2000 mg/kg (rats) 16096-31-4 1,6-bis(2,3-ethoxypropoxy)hexane Oral LD50 1400 mg/kg (rabbit) 2900 mg/kg (rats) Inhalative LC50/4 h >100 mg/l (Maus) (Contd. on page 5) GB
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Trade name: ASODUR-SG2 (A-Komp.)(INDUFLOOR-IB 1240 (A-Komp.)) (Contd. of page 4)
64742-95-6 Solvent naphtha (petroleum), light arom. Oral LD50 >2000 mg/kg (rats) Dermal LD50 >2000 mg/kg (rabbit) Inhalative LC50/4 h >5 mg/l (rats) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) EC50 (24h) 3.6 mg/l (Daphnia magna) LC50 (96h) 1.5 mg/l (rainbow trout) 64742-95-6 Solvent naphtha (petroleum), light arom. LC/EC/IC 50 1-10 mg/l (algae toxicity) 1-10 mg/l (Daphnia (acute) toxicity) · 12.2 Persistence and degradability 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) 301B (Mod. Sturm) 12 % · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES (Contd. on page 6) GB
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Trade name: ASODUR-SG2 (A-Komp.)(INDUFLOOR-IB 1240 (A-Komp.)) (Contd. of page 5)
07 02 00 07 02 99 07 00 00 07 02 00 07 02 04
wastes from the MFSU of plastics, synthetic rubber and man-made fibres wastes not otherwise specified WASTES FROM ORGANIC CHEMICAL PROCESSES wastes from the MFSU of plastics, synthetic rubber and man-made fibres other organic solvents, washing liquids and mother liquors
· Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG
· IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700)) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700)), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700))
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number:
Product contains environmentally hazardous substances: bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700) Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. (Contd. on page 7) GB
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Trade name: ASODUR-SG2 (A-Komp.)(INDUFLOOR-IB 1240 (A-Komp.)) (Contd. of page 6)
· Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category · Tunnel restriction code · UN "Model Regulation":
5L 3 E UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700)), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · National regulations · Technical instructions (air): · Class Share in % · NK 0.5 · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H340 May cause genetic defects. H350 May cause cancer. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Flam. Liq. 3: Flammable liquids – Category 3 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 (Contd. on page 8) GB
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Trade name: ASODUR-SG2 (A-Komp.)(INDUFLOOR-IB 1240 (A-Komp.)) (Contd. of page 7) Skin Sens. 1: Skin sensitisation – Category 1 Muta. 1B: Germ cell mutagenicity – Category 1B Carc. 1B: Carcinogenicity – Category 1B Asp. Tox. 1: Aspiration hazard – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB