48.0.13
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 13.02.2019 *
Version number 10
Revision: 02.11.2018
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Blankol Super · Article number: 6107 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture release agent · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS08 · Signal word Danger · Hazard-determining components of labelling: Distillates (petroleum), hydrotreated light naphthenic White spirit (incl. Petroleum 10-25%) · Hazard statements H304 May be fatal if swallowed and enters airways. · Precautionary statements P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: EUH066 Repeated exposure may cause skin dryness or cracking. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. GB
(Contd. on page 2)
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 13.02.2019
Trade name: Blankol Super (Contd. of page 1)
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Preparation, contains paraffinic and naphtenic hydrocarbons. · Dangerous components: CAS: 64742-53-6 Distillates (petroleum), hydrotreated light naphthenic EINECS: 265-156-6 Asp. Tox. 1, H304 White spirit (incl. Petroleum 10-25%) Asp. Tox. 1, H304
50-100% 10-25%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air; consult doctor in case of symptoms. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately heavy contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Do not induce vomiting; instantly call for medical help. Do not give household remedys (milk, alcohol etc.) Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. In case of strong heat burst- and explosion hazard, the pressure in the container will increase. In case of fire chill the container with water-spray. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Cool endangered containers with water spray jet. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. *
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. (Contd. on page 3) GB
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Trade name: Blankol Super (Contd. of page 2)
· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. *
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Keep away from children. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Do not spray on flames or red-hot objects. Traces of flammable substances may collect in the voids of enclosed systems. Keep ignition sources clear. Protect against electrostatic charges. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Dispose from explosive or flammable stuff. · Further information about storage conditions: Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. The usual precautionary measures should be adhered to in handling the chemicals. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 4) GB
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Trade name: Blankol Super (Contd. of page 3)
· Eye protection: Safety glasses · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Light yellow · Smell: Weak, characteristic · pH-value at 20 °C:
7.2
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: 193 °C · Flash point:
95 °C
· Ignition temperature:
240 °C
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Heating may cause an explosion.
· Critical values for explosion: Lower: Upper:
0.6 Vol % 7.0 Vol %
· Steam pressure:
Not determined.
· Density at 20 °C
0.85 g/cm³
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix
· Viscosity: dynamic: kinematic at 20 °C: · 9.2 Other information
Not determined. 14 s (ISO 4 mm) No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 64742-53-6 Distillates (petroleum), hydrotreated light naphthenic Oral LD50 >5,000 mg/kg (rats) (Contd. on page 5) GB
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Trade name: Blankol Super (Contd. of page 4)
Dermal
LD50 >5,000 mg/kg (rabbit)
White spirit (incl. Petroleum 10-25%) Oral LD50 >2,000 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rabbit) Inhalative LC 50 >5 mg/l (rats) · Primary irritant effect: · Skin corrosion/irritation Effect of degreasing. · Serious eye damage/irritation Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard May be fatal if swallowed and enters airways. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 07 00 00 Wastes from organic chemical processes 07 01 00 waste from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals 07 01 04 other organic solvents, washing liquids and mother liquors 07 00 00 Wastes from organic chemical processes 07 03 00 waste from the MFSU of organic dyes and pigments (excluding 06 11 00) 07 03 04 other organic solvents, washing liquids and mother liquors (Contd. on page 6) GB
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Trade name: Blankol Super (Contd. of page 5)
· Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · ADR
Void
· 14.2 UN proper shipping name · ADR
· 14.3 Transport hazard class(es) · ADR · Class
· 14.4 Packing group · ADR
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable.
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · National regulations · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H304 May be fatal if swallowed and enters airways. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Asp. Tox. 1: Aspiration hazard – Category 1
· * Data compared to the previous version altered. GB