50.0.4
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 27.04.2020 *
Version number 20
Revision: 27.04.2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ESCO-FLUAT · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture salt treatment (neutralization agent) · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: SDB@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Skin Corr. 1A Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Acute Tox. 4 Acute Tox. 4 Acute Tox. 4
H302 Harmful if swallowed. H312 Harmful in contact with skin. H332 Harmful if inhaled.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07, GHS09 · Signal word Danger
(Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 27.04.2020
Trade name: ESCO-FLUAT (Contd. of page 1)
· Hazard-determining components of labelling: zinc hexafluorosilicate · Hazard statements H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dusts or mists. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: aqueous hexafluorosilicate solution · Dangerous components: CAS: 16871-71-9 zinc hexafluorosilicate EINECS: 240-894-1 Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 3, H331; Skin Corr. 1A, H314; Eye Dam. 1, H318; Aquatic Acute 1, H400; Aquatic Chronic 1, H410
10-25%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Instantly remove any clothing soiled by the product. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Change immediately contaminated clothes. Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Do not induce vomiting; instantly call for medical help.
(Contd. on page 3) GB
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Trade name: ESCO-FLUAT
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.
(Contd. of page 2)
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Product is not inflammable. Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. Wear full protective suit. · Additional information Cool endangered containers with water spray jet. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. *
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle container with care. · Information about protection against explosions and fires: Protect from heat. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Provide floor trough without outlet. · Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from frost. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7 MSDS.
(Contd. on page 4) GB
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Trade name: ESCO-FLUAT (Contd. of page 3)
· 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Ensure that washing facilities are available in the work place. · Breathing equipment: Self-contained breathing apparatus must be used in case of bad fresh-air-supply or no adequate removal suction is available. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Break through time 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed safety glasses. · Body protection: Acid resistant protective clothing SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Clear · Smell: Odourless · pH-value at 20 °C:
<1
· Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: Not determined · Flash point:
Not applicable
· Self-inflammability:
Product is not selfigniting.
· Explosive properties:
Product is not explosive.
· Steam pressure:
Not determined.
· Density at 20 °C
1.18 g/cm³
· Solubility in / Miscibility with Water:
Fully miscible
· Viscosity: dynamic: kinematic:
Not determined. Not determined. (Contd. on page 5) GB
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Trade name: ESCO-FLUAT (Contd. of page 4)
· 9.2 Other information
No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Harmful if swallowed, in contact with skin or if inhaled. · LD/LC50 values that are relevant for classification: 16871-71-9 zinc hexafluorosilicate Oral LD50 100 mg/kg (Akute Toxizität) (Aligned to GHS category) Dermal LD50 300 mg/kg (Akute Toxizität) (Aligned to GHS category) Inhalative LC50/4 h 3 mg/l (Akute Toxizität) (Aligned to GHS category) · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable.
(Contd. on page 6) GB
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· vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available.
(Contd. of page 5)
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 06 00 00 WASTES FROM INORGANIC CHEMICAL PROCESSES 06 03 00 wastes from the MFSU of salts and their solutions and metallic oxides 06 03 13* solid salts and solutions containing heavy metals · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. *
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG · IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ZINC FLUOROSILICATE) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ZINC FLUOROSILICATE), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ZINC FLUOROSILICATE)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA):
Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree)
· 14.6 Special precautions for user · Kemler Number:
Warning: Miscellaneous dangerous substances and articles. 90 (Contd. on page 7) GB
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Trade name: ESCO-FLUAT (Contd. of page 6)
· EMS Number: · Segregation groups · Stowage Category
F-A,S-F Heavy metals and their salts (including their organometallic compounds) A
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · Tunnel restriction code · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ZINC FLUOROSILICATE), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E2 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H301 Toxic if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H331 Toxic if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. (Contd. on page 8) GB
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· Contact: Mr. Guido Herfort · Abbreviations and acronyms:
(Contd. of page 7)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 3: Acute toxicity - oral – Category 3 Acute Tox. 4: Acute toxicity - oral – Category 4 Skin Corr. 1A: Skin corrosion/irritation – Category 1A Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
· * Data compared to the previous version altered.
GB