57.0.19
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 03.11.2023
Version number 16 (replaces version 15)
Revision: 03.11.2023
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ESCOSIL-2000 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Spacings sealent · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-Mail: SDB@schomburg.de *
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified, according to the GB CLP regulation. · Additional information: Ensure good ventilation during application and curing. Contains the active agent biocide 2-octyl-2H-isothiazol-3-one to protect against mould infestation. Avoid contact with skin. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 Void · Hazard pictograms Void · Signal word Void · Hazard-determining components of labelling: ethyltriacetoxysilane 2-octyl-2H-isothiazol-3-one methylsilanetriyl triacetate · Hazard statements Void · 2.3 Other hazards During the processing and hardening of the material, chemical substances are released into the air (see point 11). Therefore ensure good room ventilation and, if necessary, suction. · Results of PBT and vPvB assessment · PBT: Not applicable. (Contd. on page 2) GB
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Trade name: ESCOSIL-2000 (Contd. of page 1)
· vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Mixture based on polydimethylsiloxane, fillers, additives and acetoxy- curing agent · Dangerous components: CAS: 4253-34-3 EINECS: 224-221-9 CAS: 17689-77-9
methylsilanetriyl triacetate Skin Corr. 1B, H314; Eye Dam. 1, H318, EUH014
<2.5%
ethyltriacetoxysilane Skin Corr. 1A, H314; Eye Dam. 1, H318; H302
<2.5% Acute Tox. 4,
CAS: 26530-20-1 2-octyl-2H-isothiazol-3-one <0.5% EINECS: 247-761-7 Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 2, Index number: 613-112-00-5 H330; Skin Corr. 1, H314; Eye Dam. 1, H318; Aquatic Acute 1, H400 (M=100); Aquatic Chronic 1, H410 (M=100); Skin Sens. 1A, H317, EUH071 ATE: LD50 oral: 125 mg/kg LD50 dermal: 311 mg/kg LC50/4 h inhalative: 0.27 mg/l Specific concentration limit: Skin Sens. 1A; H317: C ≥ 0.0015 % · Additional information For the wording of the listed hazard phrases refer to section 16. *
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact If skin irritation continues, consult a doctor. Wash off with soap and water. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Call a doctor immediately. Don't cause vomiting Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.
*
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Product is not inflammable. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Follow the emergency-plan. (Contd. on page 3) GB
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Trade name: ESCOSIL-2000 (Contd. of page 2)
Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. *
SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from frost. · 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 64-19-7 acetic acid, of a concentration of more than10 per cent, by weight, of acetic acid (<1%) WEL Short-term value: 50 mg/m³, 20 ppm Long-term value: 25 mg/m³, 10 ppm · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Do not eat, drink or smoke while working. Avoid contact with eyes and skin. Change clothes which heavy contaminate with the product. · Breathing equipment: Protective mask with appropriate gas filter (type ABEK according to EN 14387). · Hand protection Do not reuse one-way-gloves In case of wearing synthetic protective gloves use cotton-gloves as underwear. (Contd. on page 4) GB
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Trade name: ESCOSIL-2000 (Contd. of page 3)
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Safety glasses recommended during refilling. · Body protection: Protective work clothing. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: According to product specification · Smell: Pungent · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: Not applicable · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity Not determined. · dynamic: Not determined. · Solubility · Water: Not miscible or difficult to mix · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. · Density and/or relative density · Density not determine · Relative density Not determined. · Vapour density Not determined. · 9.2 Other information · Appearance: · Form: Pasty · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent content: · Organic solvents: 0.5 % · Solids content: 0.0 % (Contd. on page 5) GB
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Trade name: ESCOSIL-2000 (Contd. of page 4)
· Change in condition · Evaporation rate · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Not determined.
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: Avoid excessive heat. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: By heating about 150°C in present of air, could be realase small amounts of formaldehyde. *
SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 17689-77-9 ethyltriacetoxysilane Oral LD50 1,640 mg/kg (rats) (OECD 401) 64-19-7 acetic acid, of a concentration of more than10 per cent, by weight, of acetic acid Oral LD50 3,310 mg/kg (rats) 26530-20-1 2-octyl-2H-isothiazol-3-one Oral LD50 125 mg/kg (ATE) Dermal LD50 311 mg/kg (ATE) 311 mg/kg (acute toxicity) (OECD 402) Inhalative LC50/4 h 0.27 mg/l (ATE) · Primary irritant effect: No irritant action known. · Skin corrosion/irritation Based on available data, the classification criteria are not met. (Contd. on page 6) GB
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Trade name: ESCOSIL-2000 (Contd. of page 5)
· Serious eye damage/irritation Irritate-effect is possible. Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. · Other information In curing the material splits off acetic acid as vapor. This may cause irritating effects to skin, eyes or respiratory system. *
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 26530-20-1 2-octyl-2H-isothiazol-3-one EC50 (48h) 0.42 mg/l (Daphnia magna) IC50 0.084 mg/l (Scenedesmus subspicatus) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Ecotoxical effects: 26530-20-1 2-octyl-2H-isothiazol-3-one EC 50 30.4 mg/l (activated sludge bacteria) · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil.
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation A little bit of cured rubbish, cab be pushed to the household rubbish. Smaller quantities can be disposed with household garbage. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. GB
(Contd. on page 7)
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Trade name: ESCOSIL-2000 (Contd. of page 6)
SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information:
Not dangerous according to the above specifications.
· UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · National regulations · Technical instructions (air): · Class Share in % · II 0.5 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H330 Fatal if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH014 Reacts violently with water. EUH071 Corrosive to the respiratory tract. · Department issuing data specification sheet: Department EHS (Environment-Health-Safety) (Contd. on page 8) GB
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Trade name: ESCOSIL-2000 (Contd. of page 7)
Environment protection department. · Contact: Department EHS (Environment-Health-Safety) · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 3: Acute toxicity – Category 3 Acute Tox. 4: Acute toxicity – Category 4 Acute Tox. 2: Acute toxicity – Category 2 Skin Corr. 1: Skin corrosion/irritation – Category 1 Skin Corr. 1A: Skin corrosion/irritation – Category 1A Skin Corr. 1B: Skin corrosion/irritation – Category 1B Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
· * Data compared to the previous version altered. GB